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Advance in Organic Polysilazane

Sanfan Sil 5,000 t per year

Application

High-temperature corrosion

A film that stays on steel above 400 °C

The situation

Carbon steel ducting, stacks, air preheaters and furnace frames that see 400–600 °C in air, with condensate on shutdown and chlorides in the flue gas. The part is too large to stove, so the coating has to cure either at ambient or with a local heat source.

What fails today

  • Organic coatings chalk and lose gloss above 400 °C, then crack as the binder burns out.
  • Silicone coatings hold the temperature but stay soft and permeable, so chloride reaches the steel underneath.
  • Zinc-rich primers stop protecting once the zinc is consumed, which is a matter of time in a wet flue.
  • Re-coating a failed stack usually means scaffolding twice: the first failure is the expensive one.

How to apply it

Abrasive blast to Sa 2.5, or St 3 where blasting is impossible; the film does not hide a mill scale surface.

Degrease after blasting; the material reacts with water and with alcohols, so the surface must be dry and free of solvent residue.

Thin coats, not one heavy pass: the film cures by reacting with moisture and a thick layer skins over before the solvent leaves.

Cure as the grade requires, then bring the part up to temperature slowly on first service.

Do not topcoat with an amine-cured epoxy: the amine attacks the film while it is still reactive.

How to qualify it

  • Qualify on a coupon cut from the same steel, not on a polished test panel.
  • Salt spray to ISO 9227 (GB/T 10125), with and without a scribe.
  • Adhesion by cross-cut to ISO 2409 or ASTM D3359 before and after the heat cycle.
  • A thermal cycle between service temperature and ambient, then a second adhesion test: a film that survives heat but lifts on cooling has failed.
  • Pencil hardness to ISO 15184 (GB/T 6739) on the cured film, with the film thickness recorded.

Bring your substrate and your target; we quote a grade and a cure schedule against it.

Next step

Tell us the substrate and the duty